Sodium Diacetate (E262(ii))
Sodium diacetate (NaH(C₂H₃O₂)₂) is a white, crystalline, free-flowing powder with a mild acetic acid odor. It consists of sodium acetate and acetic acid in a 1:1 molar ratio. This compound is widely used as a pH regulator, preservative, and flavoring agent in food, agriculture, and industrial applications.
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Chemical Formula: NaH(C₂H₃O₂)₂
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Molecular Weight: 142.09 g/mol
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CAS Number: 126-96-5
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E Number: E262(ii)
Property | Description |
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Appearance | White crystalline powder |
Odor | Slight acetic acid smell |
Solubility | Soluble in water, slightly soluble in alcohol |
pH (1% solution) | 4.5 – 5.0 |
Melting Point | Decomposes upon heating |
Hygroscopicity | Absorbs moisture from air |
Stability | Stable under normal conditions, may degrade in high humidity |
Key Functional Properties
✔ Buffered pH Control – Maintains stable pH in food and industrial applications.
✔ Antimicrobial Activity – Inhibits bacterial and mold growth.
✔ Preservative Effect – Extends food shelf life.
✔ Flavor Enhancer – Provides a mild vinegar-like taste in seasonings.
✔ Corrosion Inhibition – Used in industrial applications for metal protection.
Sodium diacetate is produced by reacting sodium carbonate or sodium hydroxide with acetic acid under controlled conditions.
Reaction Equation:
Na₂CO₃ + 4CH₃COOH → 2NaH(C₂H₃O₂)₂ + CO₂ + H₂O
Production Process:
1️⃣ Reaction Formation: Sodium carbonate (Na₂CO₃) reacts with acetic acid (CH₃COOH) to form sodium diacetate.
2️⃣ Crystallization: The solution is evaporated to obtain solid sodium diacetate.
3️⃣ Drying & Packaging: The final product is dried and packed in moisture-resistant bags.
Raw Materials Required:
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Sodium Carbonate (Na₂CO₃) or Sodium Hydroxide (NaOH)
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Glacial Acetic Acid (CH₃COOH, >99%)
📌 Food Industry (E262(ii))
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Used in baked goods (bread, tortillas, cakes) to prevent mold growth.
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Common in meat preservation (cured meats, sausages, processed poultry).
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Enhances the flavor and stability of snacks, sauces, and spice blends.
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Controls pH levels in dairy products and beverages.
📌 Agriculture & Animal Feed
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Mold inhibitor in animal feed, preventing spoilage.
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Preserves silage and grain storage, reducing microbial damage.
📌 Industrial Applications
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Corrosion inhibitor in metal treatment and coatings.
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De-icing agent in aviation and road maintenance.
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pH stabilizer in detergents and chemical formulations.
📌 Pharmaceutical Industry
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Used in oral medications for pH control.
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Helps in buffered tablet formulations.
🔹 As a Preservative:
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Lowers food pH, inhibiting microbial growth.
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Acetic acid disrupts bacterial cell membranes, preventing proliferation.
🔹 As a pH Buffer:
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Maintains optimal pH (4.5-5.0) to prevent food spoilage due to excessive alkalinity or acidity.
🔹 As a Corrosion Inhibitor:
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Forms a protective layer on metal surfaces, reducing oxidation and corrosion.
Company | Country | Specialty |
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Niacet (A Kerry Group Company) | USA | Food-grade sodium diacetate |
Macco Organiques | Canada | High-purity sodium diacetate |
Jungbunzlauer | Switzerland | Industrial & food-grade sodium diacetate |
Jiangsu Khonor Chemicals | China | Food additives & preservatives |
Celanese Corporation | USA | Industrial and food applications |
Item | Specification |
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Appearance | White, hygroscopic crystalline solid with an acetic odor |
Free Acetic Acid (%) | 39.0 - 41.0 |
Sodium Acetate (%) | 58.0 - 60.0 |
Moisture (Karl Fischer method, %) | ≤ 2.0 |
pH (10% Solution) | 4.5 - 5.0 |
Formic Acid, Formates & Other Oxidizable (as formic acid, mg/kg) | ≤ 1000 |
Particle Size | Min 80% pass 60 mesh |
Arsenic (As, mg/kg) | ≤ 3 |
Lead (Pb, mg/kg) | ≤ 5 |
Mercury (Hg, mg/kg) | ≤ 1 |
Heavy Metal (as Pb, %) | ≤ 0.001 |
✅ Premium Quality & Food Safety Compliance – Meets FCC, E262(ii) standards.
✅ Competitive Pricing & Bulk Supply – Direct from trusted manufacturers.
✅ Fast Shipping & Custom Packaging – Available for worldwide delivery.
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